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Isocyanides as Acceptor Groups in MHAT Reactions with Unactivated Alkenes

[Image: see text] The use of isocyanides as acceptor groups in metal–hydride hydrogen atom transfer (MHAT) coupling reactions with nonactivated alkenes to form heterocycles is described. Monosubstituted alkenes couple and cyclize directly, whereas more substituted alkenes proceed via a two-step, one...

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Detalles Bibliográficos
Autores principales: Puig, Jordi, Bonjoch, Josep, Bradshaw, Ben
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10496133/
https://www.ncbi.nlm.nih.gov/pubmed/37644914
http://dx.doi.org/10.1021/acs.orglett.3c02358