Highly Reduced Ruthenium Carbide Carbonyl Clusters: Synthesis, Molecular Structure, Reactivity, Electrochemistry, and Computational Investigation of [Ru(6)C(CO)(15)](4–)

[Image: see text] The reaction of [Ru(6)C(CO)(16)](2–) (1) with NaOH in DMSO resulted in the formation of a highly reduced [Ru(6)C(CO)(15)](4–) (2), which was readily protonated by acids, such as HBF(4)·Et(2)O, to [HRu(6)C(CO)(15)](3–) (3). Oxidation of 2 with [Cp(2)Fe][PF(6)] or [C(7)H(7)][BF(4)] i...

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Detalles Bibliográficos
Autores principales: Cesari, Cristiana, Bortoluzzi, Marco, Funaioli, Tiziana, Femoni, Cristina, Iapalucci, Maria Carmela, Zacchini, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10498495/
https://www.ncbi.nlm.nih.gov/pubmed/37646082
http://dx.doi.org/10.1021/acs.inorgchem.3c01711

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10498495/
https://www.ncbi.nlm.nih.gov/pubmed/37646082
http://dx.doi.org/10.1021/acs.inorgchem.3c01711

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