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Highly Reduced Ruthenium Carbide Carbonyl Clusters: Synthesis, Molecular Structure, Reactivity, Electrochemistry, and Computational Investigation of [Ru(6)C(CO)(15)](4–)
[Image: see text] The reaction of [Ru(6)C(CO)(16)](2–) (1) with NaOH in DMSO resulted in the formation of a highly reduced [Ru(6)C(CO)(15)](4–) (2), which was readily protonated by acids, such as HBF(4)·Et(2)O, to [HRu(6)C(CO)(15)](3–) (3). Oxidation of 2 with [Cp(2)Fe][PF(6)] or [C(7)H(7)][BF(4)] i...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10498495/ https://www.ncbi.nlm.nih.gov/pubmed/37646082 http://dx.doi.org/10.1021/acs.inorgchem.3c01711 |