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From H(12)C(4)N(2)CdI(4) to H(11)C(4)N(2)CdI(3): a highly polarizable CdNI(3) tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence

In this study, we identify a novel class of second-order nonlinear optical (NLO) crystals, non-π-conjugated piperazine (H(10)C(4)N(2), PIP) metal halides, represented by two centimeter-sized, noncentrosymmetric organic–inorganic metal halides (OIMHs), namely H(12)C(4)N(2)CdI(4) (P2(1)2(1)2(1)) and H...

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Detalles Bibliográficos
Autores principales: Wu, Huai-Yu, Hu, Chun-Li, Xu, Miao-Bin, Chen, Qian-Qian, Ma, Nan, Huang, Xiao-Ying, Du, Ke-Zhao, Chen, Jin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10498671/
https://www.ncbi.nlm.nih.gov/pubmed/37712033
http://dx.doi.org/10.1039/d3sc03052k