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From H(12)C(4)N(2)CdI(4) to H(11)C(4)N(2)CdI(3): a highly polarizable CdNI(3) tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence
In this study, we identify a novel class of second-order nonlinear optical (NLO) crystals, non-π-conjugated piperazine (H(10)C(4)N(2), PIP) metal halides, represented by two centimeter-sized, noncentrosymmetric organic–inorganic metal halides (OIMHs), namely H(12)C(4)N(2)CdI(4) (P2(1)2(1)2(1)) and H...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10498671/ https://www.ncbi.nlm.nih.gov/pubmed/37712033 http://dx.doi.org/10.1039/d3sc03052k |