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Solvent-controlled formation of alkali and alkali-earth-secured cucurbituril/guest trimers

Cucurbit[7]uril (CB[7]) encapsulates adamantyl and trimethylsilyl substituents of positively charged guests in dimethyl sulfoxide (DMSO). Unlike in water or deuterium oxide, addition of a selection of alkali and alkali-earth cations with van der Waals radii between 1.0 and 1.4 Å (Na(+), K(+), Ca(2+)...

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Detalles Bibliográficos
Autores principales: Lončarić, Doroteja, Movahedifar, Fahimeh, Štoček, Jakub Radek, Dračínský, Martin, Cvačka, Josef, Guan, Shanshan, Bythell, Benjamin J., Císařová, Ivana, Masson, Eric, Kaleta, Jiří
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10498720/
https://www.ncbi.nlm.nih.gov/pubmed/37712024
http://dx.doi.org/10.1039/d3sc02032k