Geminal parahydrogen-induced polarization: accumulating long-lived singlet order on methylene proton pairs

In the majority of hydrogenative parahydrogen-induced polarization (PHIP) experiments, the hydrogen molecule undergoes pairwise cis addition to an unsaturated precursor to occupy vicinal positions on the product molecule. However, some ruthenium-based hydrogenation catalysts induce geminal hydrogena...

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Detalles Bibliográficos
Autores principales: Dagys, Laurynas, Ripka, Barbara, Leutzsch, Markus, Moustafa, Gamal A. I., Eills, James, Colell, Johannes F. P., Levitt, Malcolm H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Copernicus GmbH 2020
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10500696/
https://www.ncbi.nlm.nih.gov/pubmed/37904826
http://dx.doi.org/10.5194/mr-1-175-2020

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10500696/
https://www.ncbi.nlm.nih.gov/pubmed/37904826
http://dx.doi.org/10.5194/mr-1-175-2020

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