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Decarboxylation of β-boryl NHPI esters enables radical 1,2-boron shift for the assembly of versatile organoborons

In recent years, numerous 1,2-R shift (R = aliphatic or aryl) based on tetracoordinate boron species have been well investigated. In the contrary, the corresponding radical migrations, especially 1,2-boryl radical shift for the construction of organoborons is still in its infancy. Given the paucity...

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Detalles Bibliográficos
Autores principales: Guo, Yu, Wang, Xiaosha, Li, Chengbo, Su, Jianke, Xu, Jian, Song, Qiuling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10502150/
https://www.ncbi.nlm.nih.gov/pubmed/37709736
http://dx.doi.org/10.1038/s41467-023-41254-1