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Methyl radical chemistry in non-oxidative methane activation over metal single sites

Molybdenum supported on zeolites has been extensively studied as a catalyst for methane dehydroaromatization. Despite significant progress, the actual intermediates and particularly the first C-C bond formation have not yet been elucidated. Herein we report evolution of methyl radicals during non-ox...

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Detalles Bibliográficos
Autores principales: Huang, Xin, Eggart, Daniel, Qin, Gangqiang, Sarma, Bidyut Bikash, Gaur, Abhijeet, Yang, Jiuzhong, Pan, Yang, Li, Mingrun, Hao, Jianqi, Yu, Hongfei, Zimina, Anna, Guo, Xiaoguang, Xiao, Jianping, Grunwaldt, Jan-Dierk, Pan, Xiulian, Bao, Xinhe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10504359/
https://www.ncbi.nlm.nih.gov/pubmed/37714864
http://dx.doi.org/10.1038/s41467-023-41192-y