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Organocatalyzed ring-opening reactions of γ-carbonyl-substituted ε-caprolactones

Side-chain-functionalized aliphatic polyesters are promising as functional biodegradable polymers. We have investigated ring-opening reactions of γ-carbonyl-substituted ε-caprolactones (gCCLs) to obtain poly(ε-caprolactone) (PCL) analogues. Organic catalysts and Sn(Oct)(2) often used for the ring-op...

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Detalles Bibliográficos
Autores principales: Ota, Takayuki, Montagna, Valentina, Higuchi, Yuji, Kato, Takashi, Tanaka, Masaru, Sardon, Haritz, Fukushima, Kazuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10507672/
https://www.ncbi.nlm.nih.gov/pubmed/37731833
http://dx.doi.org/10.1039/d3ra01025b