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Stereospecific Synthesis of Cyclohexenone Acids by [3,3]-Sigmatropic Rearrangement Route

[Image: see text] Herein we report a modular synthetic method for the preparation of diaryl-substituted cyclohexenone acids starting from phenyl pyruvate and suitable enones. When the reaction is carried out in alkaline tert-butanol or toluene solutions in microwave-assisted conditions mainly anti c...

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Detalles Bibliográficos
Autores principales: Eronen, Aleksi, Nieger, Martin, Kajander, Tommi A., Repo, Timo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10507681/
https://www.ncbi.nlm.nih.gov/pubmed/37656942
http://dx.doi.org/10.1021/acs.joc.3c00757