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Elucidation of the stereocontrol mechanisms of the chemical and biosynthetic intramolecular Diels–Alder cycloaddition for the formation of bioactive decalins

The intramolecular Diels–Alder reaction (IMDA) is a powerful method for regioselective and stereoselective construction of functionalised decalin skeletons, and the recent discovery of enzymes that catalyse IMDA cycloaddition in biosynthesis has generated considerable interest. This study focused on...

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Detalles Bibliográficos
Autores principales: Kariya, Takumi, Hasegawa, Hayato, Udagawa, Taro, Inada, Yusaku, Nishiyama, Kyoko, Tsuji, Mieko, Hirayama, Tasuku, Suzutani, Tatsuo, Kato, Naoki, Nagano, Shingo, Nagasawa, Hideko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10508222/
https://www.ncbi.nlm.nih.gov/pubmed/37731829
http://dx.doi.org/10.1039/d3ra04406h