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Visible-light-induced nickel-catalyzed α-hydroxytrifluoroethylation of alkyl carboxylic acids: Access to trifluoromethyl alkyl acyloins

A visible-light-induced nickel-catalyzed cross coupling of alkyl carboxylic acids with N-trifluoroethoxyphthalimide is described. Under purple light irradiation, an α-hydroxytrifluoroethyl radical generated from a photoactive electron donor–acceptor complex between Hantzsch ester and N-trifluoroetho...

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Detalles Bibliográficos
Autores principales: Chen, Feng, Xu, Xiu-Hua, Chen, Zeng-Hao, Chen, Yue, Qing, Feng-Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10509543/
https://www.ncbi.nlm.nih.gov/pubmed/37736392
http://dx.doi.org/10.3762/bjoc.19.98