Cargando…
Late-Stage Molecular Editing Enabled by Ketone Chain-Walking Isomerization
[Image: see text] Herein, a method for the isomerization of ketones in a manner akin to the chain-walking reaction of alkenes is described. Widely available and inexpensive pyrrolidine and elemental sulfur are deployed as catalysts to achieve this reversible transformation. Key to the utility of thi...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10510328/ https://www.ncbi.nlm.nih.gov/pubmed/37640367 http://dx.doi.org/10.1021/jacs.3c05680 |