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Why surface hydrophobicity promotes CO(2) electroreduction: a case study of hydrophobic polymer N-heterocyclic carbenes

We report the use of polymer N-heterocyclic carbenes (NHCs) to control the microenvironment surrounding metal nanocatalysts, thereby enhancing their catalytic performance in CO(2) electroreduction. Three polymer NHC ligands were designed with different hydrophobicity: hydrophilic poly(ethylene oxide...

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Detalles Bibliográficos
Autores principales: Luo, Qiang, Duan, Hanyi, McLaughlin, Michael C., Wei, Kecheng, Tapia, Joseph, Adewuyi, Joseph A., Shuster, Seth, Liaqat, Maham, Suib, Steven L., Ung, Gaël, Bai, Peng, Sun, Shouheng, He, Jie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10510627/
https://www.ncbi.nlm.nih.gov/pubmed/37736633
http://dx.doi.org/10.1039/d3sc02658b