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Guest-induced pore breathing controls the spin state in a cyanido-bridged framework

Iron(ii) spin cross-over (SCO) compounds combine a thermally driven transition from the diamagnetic low-spin (LS) state to the paramagnetic high-spin (HS) state with a distinct change in the crystal lattice volume. Inversely, if the crystal lattice volume was modulated post-synthetically, the spin s...

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Detalles Bibliográficos
Autores principales: Magott, Michał, Płonka, Klaudia, Sieklucka, Barbara, Dziedzic-Kocurek, Katarzyna, Kosaka, Wataru, Miyasaka, Hitoshi, Pinkowicz, Dawid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10510767/
https://www.ncbi.nlm.nih.gov/pubmed/37736640
http://dx.doi.org/10.1039/d3sc03255h