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Gas-phase preparation of azulene (C(10)H(8)) and naphthalene (C(10)H(8)) via the reaction of the resonantly stabilized fulvenallenyl (C(7)H(5)˙) and propargyl (C(3)H(3)˙) radicals

Synthetic routes to the 10π Hückel aromatic azulene (C(10)H(8)) molecule, the simplest polycyclic aromatic hydrocarbon carrying an adjacent five- and seven-membered ring, have been of fundamental importance due to the role of azulene – a structural isomer of naphthalene – as an essential molecular b...

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Detalles Bibliográficos
Autores principales: Li, Wang, Yang, Jiuzhong, Zhao, Long, Couch, David, Marchi, Myrsini San, Hansen, Nils, Morozov, Alexander N., Mebel, Alexander M., Kaiser, Ralf I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10510771/
https://www.ncbi.nlm.nih.gov/pubmed/37736626
http://dx.doi.org/10.1039/d3sc03231k