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Gas-phase preparation of azulene (C(10)H(8)) and naphthalene (C(10)H(8)) via the reaction of the resonantly stabilized fulvenallenyl (C(7)H(5)˙) and propargyl (C(3)H(3)˙) radicals
Synthetic routes to the 10π Hückel aromatic azulene (C(10)H(8)) molecule, the simplest polycyclic aromatic hydrocarbon carrying an adjacent five- and seven-membered ring, have been of fundamental importance due to the role of azulene – a structural isomer of naphthalene – as an essential molecular b...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10510771/ https://www.ncbi.nlm.nih.gov/pubmed/37736626 http://dx.doi.org/10.1039/d3sc03231k |