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A unified strategy for the synthesis of aldohexoses by boronate assisted assembly of CH(2)X(2) derived C(1)-building blocks
A synthetic strategy for all aldohexoses with individually addressable protecting groups from dihalomethane C(1)-units is reported. The underlying synthesis of C(6)-sugar alcohols relies on three consecutive Matteson sequences, vinylation and bishydroxylation. Erythro and threo isomers have been rea...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10510816/ https://www.ncbi.nlm.nih.gov/pubmed/37736647 http://dx.doi.org/10.1039/d3sc03778a |