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Strong structuring arising from weak cooperative O-H···π and C-H···O hydrogen bonding in benzene-methanol solution

Weak hydrogen bonds, such as O-H···π and C-H···O, are thought to direct biochemical assembly, molecular recognition, and chemical selectivity but are seldom observed in solution. We have used neutron diffraction combined with H/D isotopic substitution to obtain a detailed spatial and orientational p...

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Detalles Bibliográficos
Autores principales: Di Mino, Camilla, Seel, Andrew G., Clancy, Adam J., Headen, Thomas F., Földes, Támas, Rosta, Edina, Sella, Andrea, Skipper, Neal T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10516861/
https://www.ncbi.nlm.nih.gov/pubmed/37736749
http://dx.doi.org/10.1038/s41467-023-41451-y