Cargando…

Strong structuring arising from weak cooperative O-H···π and C-H···O hydrogen bonding in benzene-methanol solution

Weak hydrogen bonds, such as O-H···π and C-H···O, are thought to direct biochemical assembly, molecular recognition, and chemical selectivity but are seldom observed in solution. We have used neutron diffraction combined with H/D isotopic substitution to obtain a detailed spatial and orientational p...

Descripción completa

Detalles Bibliográficos
Autores principales:	Di Mino, Camilla, Seel, Andrew G., Clancy, Adam J., Headen, Thomas F., Földes, Támas, Rosta, Edina, Sella, Andrea, Skipper, Neal T.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10516861/ https://www.ncbi.nlm.nih.gov/pubmed/37736749 http://dx.doi.org/10.1038/s41467-023-41451-y

Ejemplares similares

Weak Interactions in Dimethyl Sulfoxide (DMSO)–Tertiary Amide Solutions: The Versatility of DMSO as a Solvent
por: Di Mino, Camilla, et al.
Publicado: (2023)

Intermediate Range Order in Metal–Ammonia Solutions: Pure and Na-Doped Ca-NH(3)
por: Nicholas, Thomas C., et al.
Publicado: (2021)

Thermodynamics of π–π Interactions of Benzene and Phenol in Water
por: Paik, Dooam, et al.
Publicado: (2022)

1,4-Bis(1H-benzimidazol-2-yl)benzene methanol monosolvate
por: Su, Jiang-Bo, et al.
Publicado: (2010)

Weak interactions but potent effect: tunable mechanoluminescence by adjusting intermolecular C–H···π interactions
por: Xie, Zongliang, et al.
Publicado: (2018)

The Influence of Weakly Coordinating Cations on the O−H⋅⋅⋅O(−) Hydrogen Bond of Silanol‐Silanolate Anions
por: Weitkamp, Robin F., et al.
Publicado: (2020)

Calcium Inhibition of Ribonuclease H1 Two-Metal Ion Catalysis
por: Rosta, Edina, et al.
Publicado: (2014)

Rhoda‐Electrocatalyzed Bimetallic C−H Oxygenation by Weak O‐Coordination
por: Tan, Xuefeng, et al.
Publicado: (2021)

Nature of intramolecular O–H⋯π interactions as elucidated by QTAIM dual functional analysis with QC calculations
por: Hayashi, Satoko, et al.
Publicado: (2019)

Comparative Structural Study of Three Tetrahalophthalic Anhydrides: Recognition of X···O(anhydride) Halogen Bond and πh···O(anhydride) Interaction
por: Baykov, Sergey V., et al.
Publicado: (2021)

Reinvestigation of the crystal structure of N-(4-chlorobenzylidene)-2-hydroxyaniline: a three-dimensional structure containing O—H⋯N, O—H⋯O and C—H⋯π(arene) hydrogen bonds
por: Girisha, Marisiddaiah, et al.
Publicado: (2018)

DFT investigation of role of N – H⋯O and N – H⋯π interactions in the stabilization of the hydrogen bonded complexes of anisole with aromatic amines
por: Rajpurohit, Anil Singh, et al.
Publicado: (2019)

Selective Oxidation of Methane to Methanol via In Situ H(2)O(2) Synthesis
por: Ni, Fenglou, et al.
Publicado: (2023)

An efficient photocatalyst based on H(5)PMo(10)V(2)O(40)/UiO-66-NH(2) for direct hydroxylation of benzene to phenol by H(2)O(2)
por: Jia, Xu, et al.
Publicado: (2022)

An exploration of O—H⋯O and C—H⋯π interactions in a long-chain-ester-substituted phenylphenol: methyl 10-[4-(4-hydroxyphenyl)phenoxy]decanoate
por: Geiger, David K., et al.
Publicado: (2018)

Collective Mid-Infrared Vibrations in Surface-Enhanced Raman Scattering
por: Mueller, Niclas S., et al.
Publicado: (2022)

Engineering nanoscale H supply chain to accelerate methanol synthesis on ZnZrO(x)
por: Lee, Kyungho, et al.
Publicado: (2023)

Synergistic effect of hydrogen bonds and π-π interactions of B(C(6)F(5))(3)·H(2)O/amides complex: Application in photoredox catalysis
por: Wang, Shi-Jun, et al.
Publicado: (2023)

Theoretical and experimental studies on hydrogen migration in dissociative ionization of the methanol monocation to molecular ions H(3)(+) and H(2)O(+)
por: Wu, Hua, et al.
Publicado: (2019)

Water-accelerated π-Stacking Reaction in Benzene Cluster Cation
por: Tachikawa, Hiroto, et al.
Publicado: (2019)

Bis(ethylenediamine-κ(2) N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvate
por: Abbaszadeh, Abolfazl, et al.
Publicado: (2012)

Cation-π induced surface cleavage of organic pollutants with (⋅)OH formation from H(2)O for water treatment
por: Wang, Yumeng, et al.
Publicado: (2021)

Bis(4-benzoyl-3-methyl-1-phenyl-4,5-dihydro-1H-pyrazol-5-olato-κ(2) O,O′)(methanol-κO)dioxidouranium(VI) methanol monosolvate
por: Dehbi, Ouarda, et al.
Publicado: (2012)

Tuning Selectivity in the Direct Conversion of Methane to Methanol: Bimetallic Synergistic Effects on the Cleavage of C–H and O–H Bonds over NiCu/CeO(2) Catalysts
por: Lustemberg, Pablo G., et al.
Publicado: (2022)

High H(2)O(2) Utilization Promotes Selective Oxidation of Methane to Methanol at Low Temperature
por: Yan, Yang, et al.
Publicado: (2020)

The Effects of SiO(2)/Al(2)O(3) and H(2)O/Al(2)O(3) Molar Ratios on SAPO-34 Catalyst in the Methanol to Olefin Process
por: Kianfar, Ehsan
Publicado: (2022)

Mechanistic study of N–H- and H–N-codoping of a TiO(2) photocatalyst for efficient degradation of benzene under visible light
por: Li, Minghui, et al.
Publicado: (2020)

Joint neutron/X-ray crystal structure of a mechanistically relevant complex of perdeuterated urate oxidase and simulations provide insight into the hydration step of catalysis
por: McGregor, Lindsay, et al.
Publicado: (2021)

Dissecting C−H∙∙∙π and N−H∙∙∙π Interactions in Two Proteins Using a Combined Experimental and Computational Approach
por: Wang, Jia, et al.
Publicado: (2019)

H(2)O(2) photoproduction inside H(2)O and H(2)O:O(2) ices at 20–140 K
por: Kulikov, Mikhail Yu., et al.
Publicado: (2019)

Influence of Defects and H(2)O on the Hydrogenation of CO(2) to Methanol over Pt Nanoparticles in UiO-67 Metal–Organic Framework
por: Gutterød, Emil Sebastian, et al.
Publicado: (2020)

Regioselective B(3,4)–H arylation of o-carboranes by weak amide coordination at room temperature
por: Liang, Yu-Feng, et al.
Publicado: (2020)

Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis[(methanol)tris(nitrato-κ(2) O,O′)terbium(III)]
por: Jung, Yeong-Min, et al.
Publicado: (2011)

O & H’s Teeth
Publicado: (1858)

In-Situ Spectro-Electrochemistry of Conductive Polymers Using Plasmonics to Reveal Doping Mechanisms
por: Peng, Jialong, et al.
Publicado: (2022)

New insights into prediction of weak π–π complex association through proton-nuclear magnetic resonance analysis
por: Lin, Chenyu, et al.
Publicado: (2020)

Separation of halogenated benzenes enabled by investigation of halogen–π interactions with carbon materials
por: Kanao, Eisuke, et al.
Publicado: (2019)

Intramolecular Activation of C–O Bond by an o-Boryl Group in o-(Alkoxysilyl)(diarylboryl)benzenes
por: Shimizu, Tomomi, et al.
Publicado: (2019)

Crystal structures of [Mn(bdc)(Hspar)(2)(H(2)O)(0.25)]·2H(2)O containing MnO(6+1) capped trigonal prisms and [Cu(Hspar)(2)](bdc)·2H(2)O containing CuO(4) squares (Hspar = sparfloxacin and bdc = benzene-1,4-dicarboxylate)
por: An, Zhe, et al.
Publicado: (2016)

Hydrothermal synthesis of high surface area CuCrO(2) for H(2) production by methanol steam reforming
por: Huang, Rong-Jun, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_l7n73b8esfeo26kvsls1t3knq2