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Sequential Deoxygenation of CO(2) and NO(2)(–) via Redox-Control of a Pyridinediimine Ligand with a Hemilabile Phosphine
[Image: see text] The deoxygenation of environmental pollutants CO(2) and NO(2)(–) to form value-added products is reported. CO(2) reduction with subsequent CO release and NO(2)(–) conversion to NO are achieved via the starting complex Fe((PPh)PDI)Cl(2) (1). 1 contains the redox-active pyridinediimi...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10520972/ https://www.ncbi.nlm.nih.gov/pubmed/37669231 http://dx.doi.org/10.1021/acs.inorgchem.3c02323 |