Sequential Deoxygenation of CO(2) and NO(2)(–) via Redox-Control of a Pyridinediimine Ligand with a Hemilabile Phosphine

[Image: see text] The deoxygenation of environmental pollutants CO(2) and NO(2)(–) to form value-added products is reported. CO(2) reduction with subsequent CO release and NO(2)(–) conversion to NO are achieved via the starting complex Fe((PPh)PDI)Cl(2) (1). 1 contains the redox-active pyridinediimi...

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Detalles Bibliográficos
Autores principales: Lewine, Hanalei R., Teigen, Allison G., Trausch, April M., Lindblom, Kaitlyn M., Seda, Takele, Reinheimer, Eric W., Kowalczyk, Tim, Gilbertson, John D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10520972/
https://www.ncbi.nlm.nih.gov/pubmed/37669231
http://dx.doi.org/10.1021/acs.inorgchem.3c02323

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