Aluminum–Boron Bond Formation by Boron Ester Oxidative Addition at an Alumanyl Anion

[Image: see text] The potassium diamidoalumanyl, [K{Al(SiN(Dipp))}](2) (SiN(Dipp) = {CH(2)SiMe(2)NDipp}(2)), reacts with the terminal B–O bonds of pinacolato boron esters, ROBpin (R = Me, i-Pr), and B(OMe)(3) to provide potsassium (alkoxy)borylaluminate derivatives, [K{Al(SiN(Dipp))(OR)(Bpin)}](n) (...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Han-Ying, Mahon, Mary F., Hill, Michael S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10521018/
https://www.ncbi.nlm.nih.gov/pubmed/37672789
http://dx.doi.org/10.1021/acs.inorgchem.3c02566

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10521018/
https://www.ncbi.nlm.nih.gov/pubmed/37672789
http://dx.doi.org/10.1021/acs.inorgchem.3c02566

Ejemplares similares