Enantioselective Addition of Dialkyl Malonates to β-Arylethenesulfonyl Fluorides under High-Pressure Conditions

[Image: see text] Application of high-pressure conditions enables enantioselective Michael-type addition of dialkyl malonates to β-arylethenesulfonyl fluorides. The reaction is efficiently catalyzed with 5 mol % of tertiary amino-thiourea at 9 kbar. Chiral alkanesulfonyl fluorides are formed in yiel...

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Detalles Bibliográficos
Autores principales: Kopyt, Michał, Tryniszewski, Michał, Barbasiewicz, Michał, Kwiatkowski, Piotr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10521026/
https://www.ncbi.nlm.nih.gov/pubmed/37655810
http://dx.doi.org/10.1021/acs.orglett.3c02302

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10521026/
https://www.ncbi.nlm.nih.gov/pubmed/37655810
http://dx.doi.org/10.1021/acs.orglett.3c02302

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