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Mechanism and Selectivity of Copper-Catalyzed Bromination of Distal C(sp(3))–H Bonds

[Image: see text] Unactivated C(sp(3))–H bonds are the most challenging substrate class for transition metal-catalyzed C–H halogenation. Recently, the Yu group [Liu, T.; Myers, M. C.; Yu, J. Q. Angew. Chem., Int. Ed.2017, 56 (1), 306–309] has demonstrated that a Cu(II)/phenanthroline catalyst and Br...

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Detalles Bibliográficos
Autores principales: Ajitha, Manjaly J., Haines, Brandon E., Musaev, Djamaladdin G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10526628/
https://www.ncbi.nlm.nih.gov/pubmed/37772274
http://dx.doi.org/10.1021/acs.organomet.2c00554