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Base-mediated homologative rearrangement of nitrogen–oxygen bonds of N-methyl-N-oxyamides
Due to the well known reactivity of C(O)–N functionalities towards canonical C1-homologating agents (e.g. carbenoids, diazomethane, ylides), resulting in the extrusion of the N-centered fragment en route to carbonyl compounds, formal C1-insertions within N–O bonds still remain obscure. Herein, we do...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10530184/ https://www.ncbi.nlm.nih.gov/pubmed/37772102 http://dx.doi.org/10.1039/d3sc03216g |