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Asymmetry in three-site relaxation exchange NMR

The asymmetry of peak integrals in 2D relaxation maps of exchange between three sites indicates circular flow between the relaxation sites. This disagrees with the detailed balance according to which the exchange between any pair of sites must be balanced in terms of thermodynamic equilibrium. Confi...

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Detalles Bibliográficos
Autores principales: Blümich, Bernhard, Parziale, Matthew, Augustine, Matthew
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Copernicus GmbH 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10539757/
https://www.ncbi.nlm.nih.gov/pubmed/37904857
http://dx.doi.org/10.5194/mr-4-217-2023