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Electronic and ring size effects of N-heterocyclic carbenes on the kinetics of ligand substitution reactions and DNA/protein interactions of their palladium(II) complexes

The synthesis, substitution kinetics and DNA/BSA interactions of four cationic Pd(II) complexes [Pd(1)Cl]BF(4) (Pd1), [Pd(2)Cl]BF(4) (Pd2), [Pd(3)Cl]BF(4) (Pd3) and [Pd(4)Cl]BF(4) (Pd4), derived from the reaction of [PdCl(2)(NCCH(3))(2)] with ligands 2,6-bis(3-methylimidazolium-1-yl)pyridine dibromi...

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Detalles Bibliográficos
Autores principales: Omondi, Reinner O., Jaganyi, Deogratius, Ojwach, Stephen O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Netherlands 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10545578/
https://www.ncbi.nlm.nih.gov/pubmed/37184626
http://dx.doi.org/10.1007/s10534-023-00507-8