Cyclization of 1-aryl-4,4,4-trichlorobut-2-en-1-ones into 3-trichloromethylindan-1-ones in triflic acid

Trichloromethyl-substituted enones (1-aryl-4,4,4-trichlorobut-2-en-1-ones, ArCOCH=CHCCl(3), CCl(3)-enones) undergo intramolecular transformation into 3-trichloromethylindan-1-ones (CCl(3)-indanones) in Brønsted superacid CF(3)SO(3)H (triflic acid, TfOH) at 80 °C within 2–10 h in yields up to 92%. Pr...

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Detalles Bibliográficos
Autores principales: Sokolov, Vladislav A, Golushko, Andrei A, Boyarskaya, Irina A, Vasilyev, Aleksander V
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2023
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10548255/
https://www.ncbi.nlm.nih.gov/pubmed/37799178
http://dx.doi.org/10.3762/bjoc.19.105

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10548255/
https://www.ncbi.nlm.nih.gov/pubmed/37799178
http://dx.doi.org/10.3762/bjoc.19.105

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