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Buckybowl and its chiral hybrids featuring eight-membered rings and helicene units
Here we report the synthesis of a novel buckybowl (7) with a high bowl-to-bowl inversion barrier (ΔG(‡) = 38 kcal mol(−1)), which renders the rate of inversion slow enough at room temperature to establish two chiral polycyclic aromatic hydrocarbons (PAHs). By strategic fusion of eight-membered rings...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10548505/ https://www.ncbi.nlm.nih.gov/pubmed/37800001 http://dx.doi.org/10.1039/d3sc00658a |