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Biomimetic design of an α-ketoacylphosphonium-based light-activated oxygenation auxiliary

The biomimetic design of a transition metal complex based on the iron(iv)-oxo porphyrin π-cation radical species in cytochrome P450 enzymes has been studied extensively. Herein, we translate the functions of this iron(iv)-oxo porphyrin π-cation radical species to an α-ketoacyl phosphonium species co...

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Detalles Bibliográficos
Autores principales: Oya, Ryoto, Ota, Kenji, Fuki, Masaaki, Kobori, Yasuhiro, Higashi, Masahiro, Nagao, Kazunori, Ohmiya, Hirohisa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10548508/
https://www.ncbi.nlm.nih.gov/pubmed/37799983
http://dx.doi.org/10.1039/d3sc03572g