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Anomalous photochromism and mechanochromism of a linear naphthopyran enabled by a polarizing dialkylamine substituent

In contrast to common angular naphthopyrans that exhibit strong photochromic and mechanochromic behavior, constitutionally isomeric linear naphthopyrans are typically not photochromic, due to the putative instability of the completely dearomatized merocyanine product. The photochemistry of linear na...

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Detalles Bibliográficos
Autores principales: Sun, Yan, McFadden, Molly E., Osler, Skylar K., Barber, Ross W., Robb, Maxwell J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10548511/
https://www.ncbi.nlm.nih.gov/pubmed/37800007
http://dx.doi.org/10.1039/d3sc03790h