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Ruthenium(v) terminal arylimido corroles: isolation, spectroscopic characterization and reactivity

Terminal Ru(v)–imido species are thought to be as reactive to group transfer reactions as their Ru(v)–oxo homologues, but are less studied. With the electron-rich corrole ligand, relatively stable and isolable Ru(v)–arylimido complexes [Ru((t)Bu–Cor)(NAr)] (H(3)((t)Bu–Cor) = 5,15-diphenyl-10-(p-tert...

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Detalles Bibliográficos
Autores principales: Shing, Ka-Pan, Qin, Lin, Wu, Liang-Liang, Huang, Jie-Sheng, Che, Chi-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10548528/
https://www.ncbi.nlm.nih.gov/pubmed/37800003
http://dx.doi.org/10.1039/d3sc02266h