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Non-innocent Role of the Halide Ligand in the Copper-Catalyzed Olefin Aziridination Reaction

[Image: see text] In the context of copper-catalyzed nitrene transfer to olefins, many systems operate upon mixing a CuX salt (X = halide, OTf) and a polydentate N-based ligand, assuming that the X ligand is displaced from the coordination sphere toward a counterion position. Herein, we demonstrated...

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Detalles Bibliográficos
Autores principales: Rodríguez, Manuel R., M Rodríguez, Anabel, López-Resano, Sara, Pericàs, Miquel A., Díaz-Requejo, M. Mar, Maseras, Feliu, Pérez, Pedro J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10552652/
https://www.ncbi.nlm.nih.gov/pubmed/37808365
http://dx.doi.org/10.1021/acscatal.2c05069