Excited-State (Anti)Aromaticity Explains Why Azulene Disobeys Kasha’s Rule

[Image: see text] Fluorescence exclusively occurs from the lowest excited state of a given multiplicity according to Kasha’s rule. However, this rule is not obeyed by a handful of anti-Kasha fluorophores whose underlying mechanism is still understood merely on a phenomenological basis. This lack of...

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Detalles Bibliográficos
Autores principales: Dunlop, David, Ludvíková, Lucie, Banerjee, Ambar, Ottosson, Henrik, Slanina, Tomáš
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10557139/
https://www.ncbi.nlm.nih.gov/pubmed/37704031
http://dx.doi.org/10.1021/jacs.3c07625

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10557139/
https://www.ncbi.nlm.nih.gov/pubmed/37704031
http://dx.doi.org/10.1021/jacs.3c07625

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