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Asymmetric formal sp(2)-hydrocarbonations of dienes and alkynes via palladium hydride catalysis
Transition metal-catalyzed asymmetric hydrofunctionalizations of unsaturated bonds via π-ƞ(3) substitution have emerged as a reliable method to construct stereogenic centers, and mainly rely on the use of heteroatom-based or carbon nucleophiles bearing acidic C-H bonds. In comparison, sp(2) carbon n...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10562392/ https://www.ncbi.nlm.nih.gov/pubmed/37813855 http://dx.doi.org/10.1038/s41467-023-42160-2 |