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Effect of α-Substitution on the Reactivity of C(sp(3))–H Bonds in Pd(0)-Catalyzed C–H Arylation
[Image: see text] We report mechanistic studies on the reactivity of different α-substituted C(sp(3))–H bonds, −CH(n)R (R = H, Me, CO(2)Me, CONMe(2), OMe, and Ph, as well as the cyclopropyl and isopropyl derivatives −CH(CH(2))(2) and −CHMe(2)) in the context of Pd(0)-catalyzed C(sp(3))–H arylation....
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10563019/ https://www.ncbi.nlm.nih.gov/pubmed/37822862 http://dx.doi.org/10.1021/acscatal.3c03806 |