Low-Coordinate Magnesium Sulfide and Selenide Complexes

[Image: see text] The reactions of [{((iPrDip)NacNac)Mg}(2)] 1 ((iPrDip)nacnac = HC(iPrCNDip)(2)) with Ph(3)P=O at 100 °C afforded the phosphinate complex [((iPrDip)NacNac)Mg(OPPh(3))(OPPh(2))] 3. Reactions of 1 with Ph(3)P=E (E = S, Se) proceeded rapidly at room temperature to low-coordinate chalco...

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Detalles Bibliográficos
Autores principales: Burnett, Stuart, Ferns, Rochelle, Cordes, David B., Slawin, Alexandra M. Z., van Mourik, Tanja, Stasch, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10565804/
https://www.ncbi.nlm.nih.gov/pubmed/37747417
http://dx.doi.org/10.1021/acs.inorgchem.3c02132

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10565804/
https://www.ncbi.nlm.nih.gov/pubmed/37747417
http://dx.doi.org/10.1021/acs.inorgchem.3c02132

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