Seven-Membered Cyclic Diamidoalumanyls of Heavier Alkali Metals: Structures and C–H Activation of Arenes

[Image: see text] Like the previously reported potassium-based system, rubidium and cesium reduction of [{SiN(Dipp)}AlI] ({SiN(Dipp)} = {CH(2)SiMe(2)NDipp}(2)) with the heavier alkali metals [M = Rb and Cs] provides dimeric group 1 alumanyl derivatives, [{SiN(Dipp)}AlM](2). In contrast, similar trea...

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Detalles Bibliográficos
Autores principales: Liu, Han-Ying, Hill, Michael S., Mahon, Mary F., McMullin, Claire L., Schwamm, Ryan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10565898/
https://www.ncbi.nlm.nih.gov/pubmed/37829511
http://dx.doi.org/10.1021/acs.organomet.3c00323

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10565898/
https://www.ncbi.nlm.nih.gov/pubmed/37829511
http://dx.doi.org/10.1021/acs.organomet.3c00323

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