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Seven-Membered Cyclic Diamidoalumanyls of Heavier Alkali Metals: Structures and C–H Activation of Arenes
[Image: see text] Like the previously reported potassium-based system, rubidium and cesium reduction of [{SiN(Dipp)}AlI] ({SiN(Dipp)} = {CH(2)SiMe(2)NDipp}(2)) with the heavier alkali metals [M = Rb and Cs] provides dimeric group 1 alumanyl derivatives, [{SiN(Dipp)}AlM](2). In contrast, similar trea...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10565898/ https://www.ncbi.nlm.nih.gov/pubmed/37829511 http://dx.doi.org/10.1021/acs.organomet.3c00323 |