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Room temperature stable E,Z-diphosphenes: their isomerization, coordination, and cycloaddition chemistry

E,Z-isomers display distinct physical properties and chemical reactivities. However, investigations on heavy main group elements remain limited. In this work, we present the isolation and X-ray crystallographic characterization of N-heterocyclic vinyl (NHV) substituted diphosphenes as both E- and Z-...

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Detalles Bibliográficos
Autores principales: Lin, Jieli, Liu, Shihua, Zhang, Jie, Grützmacher, Hansjörg, Su, Cheng-Yong, Li, Zhongshu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10566463/
https://www.ncbi.nlm.nih.gov/pubmed/37829033
http://dx.doi.org/10.1039/d3sc04506d