Asymmetric Friedel−Crafts reaction of unsaturated carbonyl-tethered heteroarenes via vinylogous activation of Pd(0)-π-Lewis base catalysis

The alkyne group can undergo facile transformations under palladium catalysis, such as hydropalladation, Wacker reaction, etc. Here we demonstrate that a chiral Pd(0) complex can chemoselectively dihapto-coordinate to the alkyne moiety of 2-indolyl propiolates, and raise the Highest Occupied Molecul...

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Detalles Bibliográficos
Autores principales: Jiang, Bo, Gui, Wu-Tao, Wang, Hao-Tian, Xie, Ke, Chen, Zhi-Chao, Zhu, Lei, Ouyang, Qin, Du, Wei, Chen, Ying-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10566502/
https://www.ncbi.nlm.nih.gov/pubmed/37829026
http://dx.doi.org/10.1039/d3sc03996j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10566502/
https://www.ncbi.nlm.nih.gov/pubmed/37829026
http://dx.doi.org/10.1039/d3sc03996j

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