E–H Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Hydrogen and p-Block Element Hydrides

[Image: see text] Reactions of complexes [MoMCp(μ-PMes*)(CO)(6)] with H(2) and several p-block element (E) hydrides mostly resulted in the cleavage of E–H bonds under mild conditions [M = Re (1a) and Mn (1b); Mes* = 2,4,6-C(6)H(2)(t)Bu(3)]. The reaction with H(2) (ca. 4 atm) proceeded even at 295 K...

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Detalles Bibliográficos
Autores principales: Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Vega, Patricia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10568631/
https://www.ncbi.nlm.nih.gov/pubmed/37842181
http://dx.doi.org/10.1021/acs.organomet.3c00295

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10568631/
https://www.ncbi.nlm.nih.gov/pubmed/37842181
http://dx.doi.org/10.1021/acs.organomet.3c00295

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