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E–H Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Hydrogen and p-Block Element Hydrides
[Image: see text] Reactions of complexes [MoMCp(μ-PMes*)(CO)(6)] with H(2) and several p-block element (E) hydrides mostly resulted in the cleavage of E–H bonds under mild conditions [M = Re (1a) and Mn (1b); Mes* = 2,4,6-C(6)H(2)(t)Bu(3)]. The reaction with H(2) (ca. 4 atm) proceeded even at 295 K...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10568631/ https://www.ncbi.nlm.nih.gov/pubmed/37842181 http://dx.doi.org/10.1021/acs.organomet.3c00295 |