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Carbonyl-to-nickel exchange on a lactam skeleton
Molecular skeletal editing has a wide range of applications in late-stage derivatization, but metal–carbon exchange is underexplored due to the challenges in selectively cleaving highly inert chemical bonds and forming stable intermediates. Here, skeletal metalation of lactams enables a carbonyl-to-...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group UK
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10570264/ https://www.ncbi.nlm.nih.gov/pubmed/37828398 http://dx.doi.org/10.1038/s42004-023-01022-0 |