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Challenging an old paradigm by demonstrating transition metal-like chemistry at a neutral nonmetal center
We describe nonmetal adducts of the phosphorus center of terminal phosphinidene complexes using classical C- and N-ligands from metal coordination chemistry. The nature of the L-P bond has been analyzed by various theoretical methods including a refined method on the variation of the Laplacian of el...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10575908/ https://www.ncbi.nlm.nih.gov/pubmed/37833259 http://dx.doi.org/10.1038/s41467-023-42127-3 |