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The influence of substituents in governing the strength of the P–X bonds of substituted halophosphines R(1)R(2)P–X (X = F and Cl)
In this study, the gas-phase homolytic P–F and P–Cl bond dissociation energies (BDEs) of a set of thirty fluorophosphine (R(1)R(2)P–F) and thirty chlorophosphine-type (R(1)R(2)P–Cl) molecules have been obtained using the high-level W2 thermochemical protocol. For the R(1)R(2)P–F species, the P–F BDE...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Frontiers Media S.A.
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10579588/ https://www.ncbi.nlm.nih.gov/pubmed/37854977 http://dx.doi.org/10.3389/fchem.2023.1283418 |