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Phosphine-Catalyzed Domino Regio- and Stereo-Selective Hexamerization of 2-(Bromomethyl)acrylates to 1,2-Bis(cyclohexenyl)ethenyl Derivatives

[Image: see text] A phosphine-catalyzed domino assembly of six units of 2-bromomethyl acrylates afforded polyalkenyl adducts containing two cyclohexenyl rings. This reaction occurs under mild conditions providing the final product by formation of seven carbon–carbon bonds and four stereocenters. Exp...

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Detalles Bibliográficos
Autores principales: Papis, Marta, Bucci, Raffaella, Contini, Alessandro, Gelmi, Maria Luisa, Lo Presti, Leonardo, Poli, Giovanni, Broggini, Gianluigi, Loro, Camilla
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10580324/
https://www.ncbi.nlm.nih.gov/pubmed/37772494
http://dx.doi.org/10.1021/acs.orglett.3c02836