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Phosphine-Catalyzed Domino Regio- and Stereo-Selective Hexamerization of 2-(Bromomethyl)acrylates to 1,2-Bis(cyclohexenyl)ethenyl Derivatives
[Image: see text] A phosphine-catalyzed domino assembly of six units of 2-bromomethyl acrylates afforded polyalkenyl adducts containing two cyclohexenyl rings. This reaction occurs under mild conditions providing the final product by formation of seven carbon–carbon bonds and four stereocenters. Exp...
Autores principales: | Papis, Marta, Bucci, Raffaella, Contini, Alessandro, Gelmi, Maria Luisa, Lo Presti, Leonardo, Poli, Giovanni, Broggini, Gianluigi, Loro, Camilla |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10580324/ https://www.ncbi.nlm.nih.gov/pubmed/37772494 http://dx.doi.org/10.1021/acs.orglett.3c02836 |
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