Enantioselective S(N)2 Alkylation of Homoenolates by N‐Heterocyclic Carbene Catalysis

The functionalization of the β‐carbon of enals with electrophiles is a signature umpolung reactivity of N‐heterocyclic carbene (NHC) derived homoenolates. However, only a limited number of electrophiles are shown to be compatible, with most of them being π‐electrophiles. In this study, the successfu...

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Detalles Bibliográficos
Autores principales: Li, En, Tang, Kai, Ren, Zhuhui, Liao, Xiaoyun, Liu, Qianchen, Huang, Yong, Chen, Jiean
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2023
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10582416/
https://www.ncbi.nlm.nih.gov/pubmed/37541670
http://dx.doi.org/10.1002/advs.202303517

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10582416/
https://www.ncbi.nlm.nih.gov/pubmed/37541670
http://dx.doi.org/10.1002/advs.202303517

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