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Synthesis of block copolymer with cis-1,4-polybutadiene and isotactic-rich polystyrene using α-diimine nickel catalysts

A series of styrene-butadiene di-block copolymers with high cis-1,4 unit content (greater than 92%) polybutadiene (PB) and isotactic-rich polystyrene (PS) (mmmm > 65%) was synthesized using α-diimine nickel catalysts (Ni-diimine). Four different Ni-diimine catalysts were synthesized via a complex...

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Detalles Bibliográficos
Autores principales: Zheng, Nan, Liu, Jie, Li, Zonglin, Lu, Jiufu, Ni, Yan, Min, Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10582592/
https://www.ncbi.nlm.nih.gov/pubmed/37859835
http://dx.doi.org/10.1098/rsos.230791